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Angewandte Chemie International Edition

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Iron‐Catalyzed Reductive Allylic C−H Amination of Olefin with Nitroarenes via Intermolecular Nitroso Ene Reaction

1 day ago

Aromatic allylamines are essential in the synthesis of diverse pharmaceutical building blocks...

High Partial Molar Volume Polymer Electrolyte for Upgraded Lithium Metal Batteries

1 day ago

Lithium (Li) metal batteries combined with solid electrolytes represent a highly promising...

Nickel‐Catalyzed Umpolung Difluoroalkylation of Imines Enables General Access to β‐Difluoroalkylated Amines

1 day ago

Fluoroalkylated amines play a pivotal role in medicinal chemistry, yet the general...

ATP‐Assisted Electron and Proton Transfer Boosting Redox Metabolism‐Induced Ferroptosis and Apoptosis for Cancer Therapy

1 day ago

Compared to the intractability of traditional apoptosis, the vulnerability exposed by cancer...

A Hypoxia‐Triggered Bioreduction of Hydrophilic Type I Photosensitizer for Switchable In Vivo Photoacoustic Imaging and High‐Specificity Cancer Phototherapy

1 day ago

Considering that hypoxia is strongly connected with tumor proliferation, metastasis, invasion, and...

Regiospecific Halogenation Modulates Molecular Dipoles in Self‐Assembled Monolayers for High‐Performance Organic Solar Cells

1 day ago

Halogenated carbazole-derived self-assembled monolayers (SAM) are promising hole-extraction materials in conventional organic...

Rhodium‐Catalyzed 1,5‐Sigma Migratory Ring Expansion of gem‐Difluorodienyl‐Cyclopropanes and Cyclobutanes

1 day ago

Rhodium-catalyzed 1,5-sigma migratory ring expansion (SMRE) of common dieneylcyclopropanes (DECPs) and dieneylcyclobutanes...

A Metal‐Organic Framework with Tailored Shape‐matched Interactions towards Ambient‐temperature Argon Removal for Oxygen Purification

1 day ago

High-purity oxygen (O2) is essential for high-value-added applications in the medical, aerospace...

Mechanistic Insights into the CO2‐Assisted NO Electrochemical Deoxygenation and Hydrogenation

1 day ago

Electrocatalytic NO reduction to NH3 holds significant potential for pollutant treatment and...

A Bench‐stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application

1 day ago

We herein present a fluorophosphine-based nickel(0) complex [Ni(PFPh2)4] (1), which is highly...